Phosphazene-catalyzed desymmetrization of cyclohexadienones by dithiane addition
نویسندگان
چکیده
منابع مشابه
Phosphazene-catalyzed desymmetrization of cyclohexadienones by dithiane addition
We report a desymmetrization of cyclohexadienones by intramolecular conjugate addition of a tethered dithiane nucleophile. Mild reaction conditions allow the formation of diversely functionalized fused bicyclic lactones. The products participate in facially selective additions from the convex surface, leading to allylic alcohol derivatives.
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ژورنال
عنوان ژورنال: Beilstein Journal of Organic Chemistry
سال: 2017
ISSN: 1860-5397
DOI: 10.3762/bjoc.13.75